{"id":1857,"date":"2019-05-22T02:48:24","date_gmt":"2019-05-22T02:48:24","guid":{"rendered":"http:\/\/www.meetyoucarbide.com\/single-post-heat-treatment-of-tungsten-carbide-products\/"},"modified":"2020-05-04T13:12:03","modified_gmt":"2020-05-04T13:12:03","slug":"heat-treatment-of-tungsten-carbide-products","status":"publish","type":"post","link":"https:\/\/www.meetyoucarbide.com\/vi\/nhiet-luyen-san-pham-vonfram-cacbua\/","title":{"rendered":"X\u1eed l\u00fd nhi\u1ec7t c\u1ee7a c\u00e1c s\u1ea3n ph\u1ea9m cacbua vonfram"},"content":{"rendered":"
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Cacbua xi m\u0103ng (hardmetal) l\u00e0 m\u1ed9t thu\u1eadt ng\u1eef chung cho c\u00e1c h\u1ee3p kim bao g\u1ed3m c\u00e1c cacbua, nitrua, bo, ho\u1eb7c silicat c\u1ee7a c\u00e1c kim lo\u1ea1i c\u00f3 \u0111i\u1ec3m n\u00f3ng ch\u1ea3y cao (W, Mo, Ti, V, Ta, v.v.). \u0110\u01b0\u1ee3c chia th\u00e0nh hai lo\u1ea1i ch\u00ednh c\u1ee7a \u0111\u00fac v\u00e0 thi\u00eau k\u1ebft. H\u1ee3p kim \u0111\u00fac c\u00f3 \u0111\u1ed9 gi\u00f2n cao v\u00e0 \u0111\u1ed9 d\u1ebbo dai th\u1ea5p, v\u00e0 c\u00f3 \u00edt gi\u00e1 tr\u1ecb \u1ee9ng d\u1ee5ng th\u1ef1c t\u1ebf. \u0110\u01b0\u1ee3c s\u1eed d\u1ee5ng r\u1ed9ng r\u00e3i l\u00e0 c\u00e1c h\u1ee3p kim thi\u00eau k\u1ebft, th\u01b0\u1eddng \u0111\u01b0\u1ee3c thi\u00eau k\u1ebft t\u1eeb cacbua vonfram ho\u1eb7c titan cacbua v\u00e0 b\u1ed9t coban v\u00e0 c\u00f3 \u0111\u1ed9 c\u1ee9ng cao, ch\u1ed1ng m\u00e0i m\u00f2n v\u00e0 \u0111\u1ed9 c\u1ee9ng n\u00f3ng. Ch\u1ee7 y\u1ebfu \u0111\u01b0\u1ee3c s\u1eed d\u1ee5ng \u0111\u1ec3 s\u1ea3n xu\u1ea5t c\u1eaft v\u00e0 x\u1eed l\u00fd v\u1eadt li\u1ec7u c\u1ee9ng t\u1ed1c \u0111\u1ed9 cao, trong nh\u1eefng n\u0103m g\u1ea7n \u0111\u00e2y, vi\u1ec7c s\u1eed d\u1ee5ng cacbua trong ng\u00e0nh c\u00f4ng nghi\u1ec7p khu\u00f4n c\u0169ng ng\u00e0y c\u00e0ng t\u0103ng, v\u00ec v\u1eady n\u00f3 c\u00f3 \u00fd ngh\u0129a thi\u1ebft th\u1ef1c \u0111\u1ec3 th\u1ea3o lu\u1eadn v\u00e0 nghi\u00ean c\u1ee9u x\u1eed l\u00fd nhi\u1ec7t h\u1ee3p kim c\u1ee9ng.<\/div>\n

1. \u0110\u1eb7c \u0111i\u1ec3m c\u1ee7a cacbua xi m\u0103ng<\/h2>\n
Cacbua \u0111\u01b0\u1ee3c ch\u1ebf t\u1ea1o b\u1eb1ng ph\u01b0\u01a1ng ph\u00e1p luy\u1ec7n kim b\u1ed9t t\u1eeb h\u1ee3p ch\u1ea5t c\u1ee9ng kim lo\u1ea1i ch\u1ecbu l\u1eeda v\u00e0 pha li\u00ean k\u1ebft kim lo\u1ea1i. C\u00e1c h\u1ee3p ch\u1ea5t c\u1ee9ng th\u01b0\u1eddng \u0111\u01b0\u1ee3c s\u1eed d\u1ee5ng l\u00e0 cacbua. L\u00e0 h\u1ee3p kim c\u1ee9ng cho d\u1ee5ng c\u1ee5 c\u1eaft, th\u01b0\u1eddng \u0111\u01b0\u1ee3c s\u1eed d\u1ee5ng WC, TiC, TaC, NbC, v.v., ch\u1ea5t k\u1ebft d\u00ednh l\u00e0 Co v\u00e0 c\u01b0\u1eddng \u0111\u1ed9 c\u1ee7a cacbua xi m\u0103ng ch\u1ee7 y\u1ebfu ph\u1ee5 thu\u1ed9c v\u00e0o h\u00e0m l\u01b0\u1ee3ng c\u1ee7a C\u00f4ng ty v\u00ec cacbua trong cacbua xi m\u0103ng c\u00f3 \u0111i\u1ec3m n\u00f3ng ch\u1ea3y cao (nh\u01b0 nhi\u1ec7t \u0111\u1ed9 n\u00f3ng ch\u1ea3y 3140 \u00b0 C. c\u1ee7a Ti C), \u0111\u1ed9 c\u1ee9ng cao (nh\u01b0 \u0111\u1ed9 c\u1ee9ng 3200 HV c\u1ee7a TiC), \u0111\u1ed9 \u1ed5n \u0111\u1ecbnh h\u00f3a h\u1ecdc t\u1ed1t v\u00e0 \u0111\u1ed9 \u1ed5n \u0111\u1ecbnh nhi\u1ec7t t\u1ed1t, \u0111\u1ed9 c\u1ee9ng v\u00e0 ch\u1ed1ng m\u00e0i m\u00f2n ch\u00fang cao \u0110\u1ed9 \u1ed5n \u0111\u1ecbnh gi\u1edbi t\u00ednh v\u00e0 h\u00f3a h\u1ecdc cao h\u01a1n nhi\u1ec1u so v\u1edbi th\u00e9p c\u00f4ng c\u1ee5 t\u1ed1c \u0111\u1ed9 cao.<\/div>\n
Pha c\u1ee9ng cacbua th\u01b0\u1eddng \u0111\u01b0\u1ee3c s\u1eed d\u1ee5ng ch\u1ee7 y\u1ebfu l\u00e0 WC, c\u00f3 kh\u1ea3 n\u0103ng ch\u1ed1ng m\u00e0i m\u00f2n t\u1ed1t. M\u1eb7c d\u00f9 m\u1ed9t s\u1ed1 cacbua c\u00f3 \u0111\u1ed9 c\u1ee9ng t\u01b0\u01a1ng t\u1ef1 nh\u01b0 WC, nh\u01b0ng ch\u00fang kh\u00f4ng c\u00f3 kh\u1ea3 n\u0103ng ch\u1ed1ng m\u00f2n t\u01b0\u01a1ng t\u1ef1. WC c\u00f3 c\u01b0\u1eddng \u0111\u1ed9 n\u0103ng su\u1ea5t cao h\u01a1n (6000 MPa), do \u0111\u00f3 n\u00f3 c\u00f3 kh\u1ea3 n\u0103ng ch\u1ed1ng bi\u1ebfn d\u1ea1ng d\u1ebbo cao h\u01a1n. \u0110\u1ed9 d\u1eabn nhi\u1ec7t c\u1ee7a WC c\u0169ng t\u1ed1t v\u00e0 \u0111\u1ed9 d\u1eabn nhi\u1ec7t l\u00e0 m\u1ed9t ch\u1ec9 s\u1ed1 hi\u1ec7u su\u1ea5t quan tr\u1ecdng c\u1ee7a d\u1ee5ng c\u1ee5. WC c\u00f3 h\u1ec7 s\u1ed1 gi\u00e3n n\u1edf nhi\u1ec7t th\u1ea5p h\u01a1n, kho\u1ea3ng 1\/3 so v\u1edbi th\u00e9p; m\u00f4 \u0111un \u0111\u00e0n h\u1ed3i c\u1ee7a n\u00f3 g\u1ea5p 3 l\u1ea7n th\u00e9p v\u00e0 c\u01b0\u1eddng \u0111\u1ed9 n\u00e9n c\u1ee7a n\u00f3 c\u0169ng cao h\u01a1n th\u00e9p. Ngo\u00e0i ra, WC c\u00f3 kh\u1ea3 n\u0103ng ch\u1ed1ng \u0103n m\u00f2n v\u00e0 oxy h\u00f3a t\u1ed1t \u1edf nhi\u1ec7t \u0111\u1ed9 ph\u00f2ng, kh\u00e1ng \u0111i\u1ec7n t\u1ed1t v\u00e0 \u0111\u1ed9 b\u1ec1n u\u1ed1n cao.<\/div>\n

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H\u00ecnh 1 S\u01a1 \u0111\u1ed3 c\u00e2n b\u1eb1ng c\u1ee7a h\u1ee3p kim WC-Co<\/div>\n

2. T\u1ed5 ch\u1ee9c x\u1eed l\u00fd nhi\u1ec7t v\u00e0 h\u1ee3p kim<\/h2>\n
N\u00f3 \u0111\u00e3 \u0111\u01b0\u1ee3c nghi\u00ean c\u1ee9u v\u1ec1 c\u00e1c giai \u0111o\u1ea1n li\u00ean k\u1ebft c\u1ee7a h\u1ee3p kim WC-Co v\u1edbi c\u00e1c t\u1ef7 l\u1ec7 C \/ W kh\u00e1c nhau t\u1eeb 5% \u0111\u1ebfn 35% WC. C\u00e1c k\u1ebft lu\u1eadn \u0111\u01b0\u1ee3c r\u00fat ra nh\u01b0 sau: c\u00e1c pha pha ho\u1eb7c (\u03b3 + WC) \u0111\u01b0\u1ee3c t\u1ea1o ra trong h\u1ee3p kim khi l\u00e0m ngu\u1ed9i ch\u1eadm; Khi c\u00f3 (+) xu\u1ea5t hi\u1ec7n. Tuy nhi\u00ean, v\u00ec pha (\u03b3 +) kh\u00f4ng \u1ed5n \u0111\u1ecbnh, pha (\u03b3 +) s\u1ebd chuy\u1ec3n th\u00e0nh pha \u1ed5n \u0111\u1ecbnh (\u03b3 + WC) sau khi \u1ee7. Theo k\u1ebft qu\u1ea3 th\u1eed nghi\u1ec7m, s\u01a1 \u0111\u1ed3 pha c\u00e2n b\u1eb1ng b\u00e1n k\u00ednh nh\u01b0 trong h\u00ecnh 1 \u0111\u01b0\u1ee3c v\u1ebd (\u0111\u01b0\u1eddng li\u1ec1n n\u00e9t l\u00e0 s\u01a1 \u0111\u1ed3 pha c\u1ee7a h\u1ec7 \u1ed5n \u0111\u1ecbnh v\u00e0 \u0111\u01b0\u1eddng \u0111\u1ee9t n\u00e9t l\u00e0 s\u01a1 \u0111\u1ed3 pha c\u1ee5c b\u1ed9 minh h\u1ecda c\u00e1c \u0111\u1eb7c t\u00ednh c\u1ee7a \u1ed5n \u0111\u1ecbnh b\u00e1n c\u1ea7u giai \u0111o\u1ea1n).<\/div>\n
Vi\u1ec7c \u1ee7 (l\u00e0m l\u1ea1nh ch\u1eadm) c\u1ee7a cacbua xi m\u0103ng \u0111i\u1ec3n h\u00ecnh ph\u1ee5 thu\u1ed9c ch\u1ee7 y\u1ebfu v\u00e0o h\u00e0m l\u01b0\u1ee3ng carbon: khi C \/ W> 1, carbon t\u1ef1 do k\u1ebft t\u1ee7a tr\u00ean ranh gi\u1edbi pha WC-Co; khi C \/ W <1, c\u1ea5u tr\u00fac vi m\u00f4 c\u1ee7a h\u1ee3p kim c\u00f3 Trong c\u1ea3 hai tr\u01b0\u1eddng h\u1ee3p: M\u1ed9t n\u1eb1m trong v\u00f9ng ba pha (WC + +). Kh\u00f4ng th\u1ec3 tr\u00e1nh kh\u1ecfi pha appears xu\u1ea5t hi\u1ec7n sau khi h\u1ee3p kim \u0111\u01b0\u1ee3c l\u00e0m l\u1ea1nh ch\u1eadm. N\u1ebfu m\u1ed9t l\u01b0\u1ee3ng l\u1edbn pha such nh\u01b0 v\u1eady t\u1ed3n t\u1ea1i trong pha xi m\u0103ng, c\u00e1c h\u1ea1t tinh th\u1ec3 ph\u00e2n nh\u00e1nh xu\u1ea5t hi\u1ec7n v\u00e0 c\u00e1c h\u1ea1t nh\u1ecf ph\u00e2n b\u1ed1 kh\u00f4ng \u0111\u1ec1u; n\u1ebfu c\u00f3 m\u1ed9t h\u1ea1t l\u1edbn pha ,, c\u00e1c h\u1ea1t \u0111\u01b0\u1ee3c ph\u00e2n t\u00e1ch b\u1eb1ng m\u1ed9t kho\u1ea3ng c\u00e1ch d\u00e0i, do \u0111\u00f3 c\u00f3 th\u00f4ng tin r\u1eb1ng pha is l\u00e0 nhi\u1ec7t \u0111\u1ed9 cao h\u01a1n \u0111\u00e3 b\u1eaft \u0111\u1ea7u h\u00ecnh th\u00e0nh.<\/div>\n
Trong tr\u01b0\u1eddng h\u1ee3p kh\u00e1c, khi h\u1ee3p kim \u1edf v\u00f9ng hai pha (WC +), h\u1ee3p kim W s\u1ebd \u0111\u01b0\u1ee3c k\u1ebft t\u1ee7a d\u01b0\u1edbi d\u1ea1ng Co3W t\u1eeb pha li\u00ean k\u1ebft sau khi h\u1ee3p kim cacbon th\u1ea5p \u0111\u01b0\u1ee3c \u1ee7. Qu\u00e1 tr\u00ecnh ph\u1ea3n \u1ee9ng c\u00f3 th\u1ec3 \u0111\u01b0\u1ee3c th\u1ec3 hi\u1ec7n b\u1eb1ng c\u00f4ng th\u1ee9c sau \u0111\u00e2y. Kh\u1ed1i l\u1eadp ph\u01b0\u01a1ng trung t\u00e2m Co \u2192 Kh\u1ed1i l\u1eadp ph\u01b0\u01a1ng trung t\u00e2m Co + Co3W Do \u0111\u00f3, h\u1ee3p kim WC-Co hai pha c\u00f3 h\u00e0m l\u01b0\u1ee3ng carbon th\u1ea5p n\u00e0y s\u1ebd \u0111\u01b0\u1ee3c chuy\u1ec3n th\u00e0nh c\u1ea5u tr\u00fac ba pha (WC + + CoW) sau khi \u1ee7. H\u00ecnh 2 cho th\u1ea5y \u0111\u01b0\u1eddng cong h\u00f2a tan c\u1ee7a W \u0111\u1ed1i v\u1edbi h\u1ee3p kim WC-Co hai pha \u1edf c\u00e1c nhi\u1ec7t \u0111\u1ed9 \u1ee7 kh\u00e1c nhau. \u0110\u01b0\u1eddng cong l\u00e0 \u0111\u01b0\u1eddng cong nhi\u1ec7t \u0111\u1ed9 t\u1edbi h\u1ea1n \u0111\u1ed1i v\u1edbi h\u1ee3p kim hai pha \u0111\u01b0\u1ee3c chuy\u1ec3n th\u00e0nh h\u1ee3p kim ba pha (WC + \u03b3 + CoW): tr\u00ean nhi\u1ec7t \u0111\u1ed9 \u0111\u01b0\u1eddng cong K\u1ebft qu\u1ea3 luy\u1ec7n kim trong h\u1ee3p kim vi c\u1ea5u tr\u00fac hai pha; \u1ee6 \u1edf nhi\u1ec7t \u0111\u1ed9 d\u01b0\u1edbi \u0111\u01b0\u1eddng cong mang l\u1ea1i c\u1ea5u tr\u00fac ba pha c\u00f3 ch\u1ee9a Co3W.<\/div>\n

3. \u1ea2nh h\u01b0\u1edfng c\u1ee7a qu\u00e1 tr\u00ecnh x\u1eed l\u00fd nhi\u1ec7t \u0111\u1ebfn t\u00ednh ch\u1ea5t c\u01a1 h\u1ecdc c\u1ee7a h\u1ee3p kim c\u1ee9ng<\/h2>\n
(1) \u1ea2nh h\u01b0\u1edfng \u0111\u1ebfn \u0111\u1ed9 b\u1ec1n V\u00ec WC c\u00f3 \u0111\u1ed9 h\u00f2a tan r\u1eafn kh\u00e1c nhau \u1edf c\u00e1c nhi\u1ec7t \u0111\u1ed9 kh\u00e1c nhau trong Co, n\u00f3 cung c\u1ea5p kh\u1ea3 n\u0103ng l\u00e0m c\u1ee9ng k\u1ebft t\u1ee7a c\u1ee7a ch\u1ea5t k\u1ebft d\u00ednh b\u1eb1ng c\u00e1ch l\u00e0m ngu\u1ed9i nhi\u1ec7t \u0111\u1ed9 dung d\u1ecbch r\u1eafn v\u00e0 l\u00e3o h\u00f3a ti\u1ebfp theo. L\u00e0m ngu\u1ed9i c\u00f3 th\u1ec3 \u1ee9c ch\u1ebf s\u1ef1 k\u1ebft t\u1ee7a c\u1ee7a WC v\u00e0 qu\u00e1 tr\u00ecnh chuy\u1ec3n \u0111\u1ed5i \u0111\u1ed3ng \u0111\u1eb3ng c\u1ee7a Co (Co d\u00e0y \u0111\u1eb7c h\u00ecnh l\u1ee5c gi\u00e1c, Co m\u1eb7t trung t\u00e2m kh\u1ed1i). Ng\u01b0\u1eddi ta \u0111\u00e3 b\u00e1o c\u00e1o r\u1eb1ng \u0111\u1ed9 b\u1ec1n c\u1ee7a h\u1ee3p kim ch\u1ee9a coban 40% c\u00f3 th\u1ec3 t\u0103ng th\u00eam kho\u1ea3ng 10% sau khi l\u00e0m ngu\u1ed9i, nh\u01b0ng \u0111\u1ed9 b\u1ec1n c\u1ee7a h\u1ee3p kim ch\u1ee9a coban 10% b\u1ecb gi\u1ea3m sau khi l\u00e0m ngu\u1ed9i. Xem x\u00e9t r\u1eb1ng l\u01b0\u1ee3ng coban c\u00f3 trong cacbua xi m\u0103ng th\u01b0\u1eddng \u0111\u01b0\u1ee3c s\u1eed d\u1ee5ng trong k\u1ef9 thu\u1eadt th\u01b0\u1eddng l\u00e0 10% \u0111\u1ebfn 37%, \u1ea3nh h\u01b0\u1edfng c\u1ee7a x\u1eed l\u00fd nhi\u1ec7t \u0111\u1ebfn c\u01b0\u1eddng \u0111\u1ed9 h\u1ee3p kim l\u00e0 r\u1ea5t nh\u1ecf. V\u00ec v\u1eady, m\u1ed9t ng\u01b0\u1eddi n\u00e0o \u0111\u00f3 d\u00e1m kh\u1eb3ng \u0111\u1ecbnh r\u1eb1ng d\u1eadp t\u1eaft kh\u00f4ng ph\u1ea3i l\u00e0 m\u1ed9t c\u00e1ch \u0111\u1ec3 t\u0103ng s\u1ee9c m\u1ea1nh cho h\u1ee3p kim W-Co. \u1ee6 c\u0169ng l\u00e0m gi\u1ea3m \u0111\u1ed9 b\u1ec1n c\u1ee7a h\u1ee3p kim, nh\u01b0 trong B\u1ea3ng 1 v\u00e0 3. T\u00ednh ch\u1ea5t c\u1ee7a cacbua vonfram thay \u0111\u1ed5i theo l\u01b0\u1ee3ng Co ch\u1ee9a v\u00e0 \u0111\u1ed9 d\u00e0y c\u1ee7a h\u1ea1t, nh\u01b0 trong H\u00ecnh 4.<\/div>\n

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H\u00ecnh 2 \u0110\u01b0\u1eddng cong h\u00f2a tan r\u1eafn c\u1ee7a vonfram trong h\u1ee3p kim hai pha WC-10%Co<\/div>\n

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H\u00ecnh 3 \u1ea2nh h\u01b0\u1edfng c\u1ee7a \u1ee7 \u1edf 800 \u00b0 C \u0111\u1ebfn c\u01b0\u1eddng \u0111\u1ed9 u\u1ed1n c\u1ee7a n\u1ed9i dung WC-10%Co<\/div>\n